Late-Stage Transitional Boundary-Layer Structures. Direct Numerical Simulation and Experiment

This paper is devoted to direct comparisons of related, detailed experimental and numerical studies of the non-linear, late stages of laminar-turbulenttransition in a boundary layer including flow breakdown and the beginning offlow randomization. Preceding non-linear stages of the transition process arealso well documented and compared with previous studies. The experiments wereconducted with the help of a hot-wire anemometer. The numerical study wascarried out by direct numerical simulation (DNS) of the flow employing theso-called spatial approach. Both the experiments and the DNS were performed atcontrolled disturbance conditions with an excitation of instability waves inthe flat-plate boundary layer. In the two cases, the primary disturbanceconsists of a time-harmonic, two-dimensional Tollmien--Schlichting wave thathas a very weak initial spanwise modulation. Despite somewhat differentinitial disturbance conditions used in the experiment and simulation, thesubsequent flow evolution at late non-linear stages is found to be practicallythe same. Detailed qualitative and quantitative comparisons of theinstantaneous velocity and vorticity fields are performed for twocharacteristic stages of the non-linear flow breakdown: (i) “one-spike stage” and (ii) “three-spike stage.” The twoapproaches clearly show in detail the process of development of the Γ-structure, a periodical formation of ring-like vortices, the evolution of the surrounding flow field, and the beginning of flowrandomization. In particular, it is found experimentally and numerically thatthe ring-like vortices (associated with the well-known spikes) induce somerather intensive positive velocity fluctuations (positive spikes) in thenear-wall region which have the same scales as the ring-like vortices and propagate downstream with the same high (almost free-stream) speed. The positive spikes form a new high-shear layer in the near-wall region. In the experiment the induced near-wall perturbationshave a significant irregular low-frequency component. These non-periodicalmotions play an important role in the process of flow randomization and finaltransition to turbulence that starts under the ring-like vortices in thevicinity of the peak position. Received 13 December 2000 and accepted 30 October 2001     

一种铈（Ⅲ）配合物对含石墨粘结涂层耐蚀性的影响

为了改善含石墨粘结涂层的耐蚀性，首先对这种涂层在腐蚀环境中耐蚀性差的原因进行了分析，然后将二正丁基磷酸、ＣｅＦ＿３、Ｓｂ＿２Ｏ＿３和一种Ｃｅ（Ⅲ）配合物Ｃｅ（ＮＯ＿３）（Ｃ＿８Ｈ＿（１８）ＰＯ＿４）＿２分别添加于酚醛环氧－ＭｏＳ＿２－石墨粘结涂层中，考察了它们对这种涂层耐蚀性的影响，并对含Ｃｅ（ＮＯ＿３）（Ｃ＿８Ｈ＿（１８）ＰＯ＿４）＿２的涂层和空白样涂层进行了表面分析。盐雾试验表明，添加Ｃｅ（ＮＯ＿３）（Ｃ＿８Ｈ＿（１８）ＰＯ＿４）＿２可以有效地抑制涂层中ＭｏＳ＿２的氧化和由石墨所引起的金属底材之电化学腐蚀；根据Ｘ射线光电子能谱分析结果可知，添加Ｃｅ（ＮＯ＿３）（Ｃ＿８Ｈ＿（１８）ＰＯ＿４）＿２之所以能够提高含石墨粘结涂层的耐蚀性，应当归因于它在ＭｏＳ＿２晶体表面和金属底材表面的吸附。因此，Ｃｅ（Ⅲ）配合物Ｃｅ（ＮＯ＿３）（Ｃ＿８Ｈ＿（１８）ＰＯ＿４）＿２是含石墨粘结涂层的一种实用性能良好的新型防腐添加剂。     

板带轧制过程中的三维接触摩擦模型

为解决压力加工中工具与工件间的接触摩擦问题，根据金属流动对摩擦的反作用，在轧辊和工件之间引入了一层极薄的摩擦单元并将其编入三维弹塑性大变形有限元程序。通过调节摩擦元尺寸厚度和β因子，实现了对薄板轧制过程中间介质的几何尺寸模拟和物理特征模拟。该法不用对摩擦力大小、方向及中性点位置进行假定，通过计算能够得到全部有关信息。     

平板湍流边界层整体摩擦阻力的振荡性

本文分别用流场显示和阻力测量两种实验方法,证明了平板整体摩擦阻力存在着振荡性,并得到了其振荡的一些规律和特点。另外,提出了一个与时间相关联的内层速度分布模型。并对其合理性进行了研究,从而导出一个与时间相关联的整体摩擦阻力模型。     

弹塑性有限变形的拟流动理论

本文提出一种弹塑性有限变形的拟流动理论。该理论从正交性法则出发，通过引入“拟弹性模量”和模量衰减函数并改进应变率的弹塑性分解，实现了由有限变形Ｐｒａｎｄｔｌ－Ｒｅｕｓｓ流动理论（Ｊ２Ｆ）向基于非正交法则的率形式形变理论（Ｊ２Ｄ）的合理的光滑过渡；并适用于初始及后继各向异性变形分析。在特殊条件下，可退化为Ｊ２Ｆ、Ｊ２Ｄ理论以及由任意各向异性屈服函数描述的流动理论。将该理论用于韧性金属平面应力／应变拉伸失稳与变形局部化的有限元模拟，并与理论分析及实验结果相比较，表明了本文理论的正确性。     

多化学组份反应气体流动的Godunov格式

本文将单介质气体流动的Goduoov方法推广到多化学组份气体流动的计算中,建立了多化学组份气体的间断分解公式以及任意四边形网格下的Godunov方法的差分格式,提出了处理自由边界的虚相法,应用第二类网格,计算了超音速射流及其冲击问题的几个算例,并且同实验结果进行了比较。     

湍流边界层中马蹄形涡的形成方式

本文使用一种新的流动显示方法——激光片光运动法和几种实验技巧对湍流边界层中的马蹄形涡进行了观测,发现并描述了其形成的四种方式:二次不稳定式、组合式、变形式和突发式。对这四种马蹄形涡的形成及发展进行了研究和比较。实验结果表明,这些马蹄形涡在尺度、运动速度和变形上是有差别的。     

真实火箭射流冲击流场中激波结构的实验研究

本文采用一种有效的激光-莫瑞光栅干涉系统首次拍摄到真实火箭燃气射流冲击流场的激波结构.解决了长期以来无法拍摄到高温、高速、强火焰光的火箭射流流场图像的问题。利用这一系统,研究了射流冲击流场中激波结构的一些变化规律,发现了一些新的激波结构。较系统地研究了欠膨胀射流冲击各种锥体的激波形态。     

Sensory Response and Two-Photon-Fluorescence Study of Regioregular Polythiophene Nanoparticles

Nanoparticles of a regioregular and soluble polythiophene were fabricated by mini-emulsion technique. The fabricated nanoparticles were characterized by optical spectroscopy and dynamic light scattering. The fluorescence quenching of these fabricated nanoparticles with 2,4-dinitrotolune (DNT) in aqueous and organic solutions was investigated. Significant fluorescence quenching was observed. The Stern-Volmer constants were determined to be higher than that of the bulk polymer in solution, indicating that the nanoparticles provide better sensitivity in DNT sensing. Strong two-photon-induced fluorescence was measured from these nanoparticles.